It is only when a balloon is filled with a gas lighter than the air outside it that it will rise. Carbon dioxide, which you blow into a balloon from your mouth is one such gas which is lighter than air. Helium is another.

A balloon filled with helium will stay airborne as long as the gas inside and the equipment attached to it (basket, string, etc.) weigh less than the air in which it is floating.

The balloon will rise until it reaches that height where the weight of the air outside the balloon equals the weight of the air inside it. At that point, it begins to float.

Gradually, though, the air inside does begin to leak out and the balloon starts to fall to earth.